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Carbon-14 decays with a half life of about 5730 years by the emission of an electron of energy 0.016 MeV. This changes the atomic number of the nucleus to 7

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Infrared spectroscopy can detect trace gases and potentially provide an alternative carbon dating technique.

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For an example, when they tried to get the carbon dating for presence of Aboriginal people in Australia they get to the number 40,000. But it could be much earlier.

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